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1

Regioselective rhodium-catalyzed intermolecular [2+2+2] cycloaddition of alkynes and isocyanates to form pyridones

Kevin M. Oberg, Ernest E. Lee, Tomislav Rovis

Journal:

Year:

2009

Language:

english

File:

PDF, 354 KB

english, 2009

2

Selective functionalization of 1,2-dihydronaphthalenols leads to a concise, stereoselective synthesis of sertraline

Mark Lautens, Tomislav Rovis

Journal:

Year:

1999

Language:

english

File:

PDF, 630 KB

english, 1999

3

Rhodium-catalysed syn-carboamination of alkenes via a transient directing group

Piou, Tiffany, Rovis, Tomislav

Journal:

Year:

2015

Language:

english

File:

PDF, 501 KB

english, 2015

4

Complementary Strategies for Directed C(sp 3 )−H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer

Chu, John C. K., Rovis, Tomislav

Journal:

Angewandte Chemie International Edition

Year:

2017

Language:

english

File:

PDF, 4.99 MB

english, 2017

5

Cluster Preface: Alkene Halofunctionalization

Johnston, Jeffrey, Rovis, Tomislav

Journal:

Year:

2018

Language:

english

File:

PDF, 406 KB

english, 2018

6

Beyond Reppe: Building Substituted Arenes by [2+2+2] Cycloadditions of Alkynes

Brandon R. Galan, Tomislav Rovis

Journal:

Angewandte Chemie International Edition

Year:

2009

Language:

english

File:

PDF, 302 KB

english, 2009

7

Enantioselective Rhodium-Catalyzed [4 + 2] Cycloaddition of α,β-Unsaturated Imines and Isocyanates

Oberg, Kevin M., Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2011

Language:

english

File:

PDF, 832 KB

english, 2011

8

An Efficient Synthesis of Achiral and Chiral 1,2,4-Triazolium Salts: Bench Stable Precursors for N - Heterocyclic Carbenes

Kerr, Mark S., Read de Alaniz, Javier, Rovis, Tomislav

Journal:

Journal of Organic Chemistry

Year:

2005

Language:

english

File:

PDF, 217 KB

english, 2005

9

Multi-component cycloaddition approaches in the catalytic asymmetric synthesis of alkaloid targets

Perreault, Stéphane, Rovis, Tomislav

Journal:

Chemical Society Reviews

Year:

2009

Language:

english

File:

PDF, 2.35 MB

english, 2009

10

Enantioselective Rhodium-Catalyzed [2 + 2 + 2] Cycloadditions of Terminal Alkynes and Alkenyl Isocyanates: Mechanistic Insights Lead to a Unified Model that Rationalizes Product Selectivity

Dalton, Derek M., Oberg, Kevin M., Yu, Robert T., Lee, Ernest E., Perreault, Stéphane, Oinen, Mark Emil, Pease, Melissa L., Malik, Guillaume, Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2009

Language:

english

File:

PDF, 3.82 MB

english, 2009

11

Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity

Lautens, Mark, Chiu, Pauline, Ma, Shihong, Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

1995

Language:

english

File:

PDF, 311 KB

english, 1995

12

The Comprehensive e-Book of Named Organic Reactions and Their Mechanisms By Elbertus Kruiswijk. The Chemical Bookstore: Aberaman, U.K. 2005. http://www.namedorganicreactions.co.uk. 1980 pp. Approximately $23.00.

Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2005

Language:

english

File:

PDF, 21 KB

english, 2005

13

Enantioselective Rhodium-Catalyzed [4+2+2] Cycloaddition of Dienyl Isocyanates for the Synthesis of Bicyclic Azocine Rings

Yu, Robert T., Friedman, Rebecca Keller, Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2009

Language:

english

File:

PDF, 244 KB

english, 2009

14

Stereoelectronic Basis for the Kinetic Resolution of N-Heterocycles with Chiral Acylating Reagents

Hsieh, Sheng-Ying, Wanner, Benedikt, Wheeler, Philip, Beauchemin, André M., Rovis, Tomislav, Bode, Jeffrey W.

Journal:

Chemistry - A European Journal

Year:

2014

Language:

english

File:

PDF, 506 KB

english, 2014

15

Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes: Application to the Total Synthesis of (+)-Lasubine II

Yu, Robert T., Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2006

Language:

english

File:

PDF, 83 KB

english, 2006

16

Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Alkynes

Yu, Robert T., Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2006

Language:

english

File:

PDF, 71 KB

english, 2006

17

Enantioselective Synthesis of Indolizidines Bearing Quaternary Substituted Stereocenters via Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes

Lee, Ernest E., Rovis, Tomislav

Journal:

Organic Letters

Year:

2008

Language:

english

File:

PDF, 97 KB

english, 2008

18

Excess Substrate is a Spectator Ligand in a Rhodium-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates with Tolanes

Oinen, Mark Emil, Yu, Robert T., Rovis, Tomislav

Journal:

Organic Letters

Year:

2009

Language:

english

File:

PDF, 534 KB

english, 2009

19

Predictable and Regioselective Insertion of Internal Unsymmetrical Alkynes in Rhodium-Catalyzed Cycloadditions with Alkenyl Isocyanates

Friedman, Rebecca Keller, Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2009

Language:

english

File:

PDF, 861 KB

english, 2009

20

Pyridine synthesis by [4 + 2] cycloadditions of 1-azadienes: hetero-Diels Alder and transition metal-catalysed approaches

Neely, Jamie M., Rovis, Tomislav

Journal:

Organic Chemistry Frontiers

Year:

2014

Language:

english

File:

PDF, 2.10 MB

english, 2014

21

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

Flanigan, Darrin M., Romanov-Michailidis, Fedor, White, Nicholas A., Rovis, Tomislav

Journal:

Chemical Reviews

Year:

2015

Language:

english

File:

PDF, 14.91 MB

english, 2015

22

Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C–H Activation

Romanov-Michailidis, Fedor, Sedillo, Kassandra F., Neely, Jamie M., Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2015

Language:

english

File:

PDF, 655 KB

english, 2015

23

Organic chemistry: Natural polarity inverted

Romanov-Michailidis, Fedor, Rovis, Tomislav

Journal:

Year:

2015

Language:

english

File:

PDF, 223 KB

english, 2015

24

17th IUPAC Conference on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 17), Fort Collins, CO, USA, July 28–August 1, 2013

Ferreira, Eric M., Rovis, Tomislav

Journal:

Green Processing and Synthesis

Year:

2013

Language:

english

File:

PDF, 320 KB

english, 2013

25

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

Chu, John C. K., Rovis, Tomislav

Journal:

Year:

2016

Language:

english

File:

PDF, 300 KB

english, 2016

26

Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C–H Functionalization

Piou, Tiffany, Rovis, Tomislav

Journal:

Accounts of Chemical Research

Year:

2017

Language:

english

File:

PDF, 3.03 MB

english, 2017

27

Generation of Phosphoranyl Radicals via Photoredox Catalysis Enables Voltage–Independent Activation of Strong C–O Bonds

Stache, Erin E, Ertel, Alyssa B., Rovis, Tomislav, Doyle, Abigail G.

Journal:

Year:

2018

Language:

english

File:

PDF, 576 KB

english, 2018

28

Photoredox catalysis using infrared light via triplet fusion upconversion

Ravetz, Benjamin D., Pun, Andrew B., Churchill, Emily M., Congreve, Daniel N., Rovis, Tomislav, Campos, Luis M.

Journal:

Year:

2019

Language:

english

File:

PDF, 1.66 MB

english, 2019

29

A Rh(III)-Catalyzed Formal [4+1] Approach to Pyrrolidines from Unactivated Terminal Alkenes and Nitrene Sources

Lee, Sumin, Lei, Honghui, Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2019

Language:

english

File:

PDF, 944 KB

english, 2019

30

Regioselective Alkylative Cross-Coupling of Remote Unactivated C( sp 3 )–H Bonds

Thullen, Scott M., Treacy, Sean M., Rovis, Tomislav

Journal:

Journal of the American Chemical Society

Year:

2019

Language:

english

File:

PDF, 1.21 MB

english, 2019

31

Stereoselective Lewis Acid Mediated [1,3] Ring Contraction of 2,5-Dihydrooxepins as a Route to Polysubstituted Cyclopentenes

Christopher G. Nasveschuk, Tomislav Rovis

Journal:

Angewandte Chemie

Year:

2005

Language:

english

File:

PDF, 303 KB

english, 2005

32

Nicht ganz unbeteiligt: der Einfluss von Olefinen auf übergangsmetallkatalysierte Kreuzkupplungen

Jeffrey B. Johnson, Tomislav Rovis

Journal:

Angewandte Chemie

Year:

2008

Language:

german

File:

PDF, 1.19 MB

german, 2008

33

A Concise Synthesis of Eupomatilones 4, 6, and 7 by Rhodium-Catalyzed Enantioselective Desymmetrization of Cyclic meso Anhydrides with Organozinc Reagents Generated In Situ

Jeffrey B. Johnson, Eric A. Bercot, Catherine M. Williams, Tomislav Rovis

Journal:

Angewandte Chemie

Year:

2007

Language:

english

File:

PDF, 154 KB

english, 2007

34

Alkene-Directed Regioselective Nickel-Catalyzed Cross-Coupling of Cyclic Anhydrides with Diorganozinc Reagents

Rebecca L. Rogers, Jennifer L. Moore, Tomislav Rovis

Journal:

Angewandte Chemie

Year:

2007

Language:

english

File:

PDF, 360 KB

english, 2007

35

Über Reppe hinaus: Aufbau substituierter Arene durch [2+2+2]-Cycloaddition von Alkinen

Brandon R. Galan, Tomislav Rovis

Journal:

Angewandte Chemie

Year:

2009

Language:

german

File:

PDF, 303 KB

german, 2009

36

Total Synthesis of Indolizidine Alkaloid (−)-209D: Overriding Substrate Bias in the Asymmetric Rhodium-Catalyzed [2+2+2] Cycloaddition

Robert T. Yu, Ernest E. Lee, Guillaume Malik, Tomislav Rovis

Journal:

Angewandte Chemie

Year:

2009

Language:

english

File:

PDF, 368 KB

english, 2009

37

Stereoselective Lewis Acid Mediated [1,3] Ring Contraction of 2,5-Dihydrooxepins as a Route to Polysubstituted Cyclopentenes

Christopher G. Nasveschuk, Tomislav Rovis

Journal:

Angewandte Chemie International Edition

Year:

2005

Language:

english

File:

PDF, 303 KB

english, 2005

38

More than Bystanders: The Effect of Olefins on Transition-Metal-Catalyzed Cross-Coupling Reactions

Jeffrey B. Johnson, Tomislav Rovis

Journal:

Angewandte Chemie International Edition

Year:

2008

Language:

english

File:

PDF, 1.17 MB

english, 2008

39

A Concise Synthesis of Eupomatilones 4, 6, and 7 by Rhodium-Catalyzed Enantioselective Desymmetrization of Cyclic meso Anhydrides with Organozinc Reagents Generated In Situ

Jeffrey B. Johnson, Eric A. Bercot, Catherine M. Williams, Tomislav Rovis

Journal:

Angewandte Chemie International Edition

Year:

2007

Language:

english

File:

PDF, 154 KB

english, 2007

40

Alkene-Directed Regioselective Nickel-Catalyzed Cross-Coupling of Cyclic Anhydrides with Diorganozinc Reagents

Rebecca L. Rogers, Jennifer L. Moore, Tomislav Rovis

Journal:

Angewandte Chemie International Edition

Year:

2007

Language:

english

File:

PDF, 360 KB

english, 2007

41

Total Synthesis of Indolizidine Alkaloid (−)-209D: Overriding Substrate Bias in the Asymmetric Rhodium-Catalyzed [2+2+2] Cycloaddition

Robert T. Yu, Ernest E. Lee, Guillaume Malik, Tomislav Rovis

Journal:

Angewandte Chemie International Edition

Year:

2009

Language:

english

File:

PDF, 368 KB

english, 2009

42

Organocatalytic Hydroacylation of Unactivated Alkenes

Daniel A. DiRocco, Prof. Dr. Tomislav Rovis

Journal:

Angewandte Chemie International Edition

Year:

2011

Language:

english

File:

PDF, 274 KB

english, 2011

43

Catalytic Asymmetric Intermolecular Stetter Reactions of Enolizable Aldehydes with Nitrostyrenes: Computational Study Provides Insight into the Success of the Catalyst

Daniel A. DiRocco, Elizabeth L. Noey, Prof. K. N. Houk, Prof. Tomislav Rovis

Journal:

Angewandte Chemie International Edition

Year:

2012

Language:

english

File:

PDF, 674 KB

english, 2012

44

ChemInform Abstract: Selective Functionalization of 1,2-Dihydronaphthalenols Leads to a Concise, Stereoselective Synthesis of Sertraline.

Mark Lautens, Tomislav Rovis

Journal:

Year:

1999

File:

PDF, 30 KB

1999

45

ChemInform Abstract: Hydroalumination of Carbon—Carbon Double Bonds

Mark Lautens, Tomislav Rovis

Journal:

Year:

2000

File:

PDF, 24 KB

2000

46

ChemInform Abstract: Chiral Copper(II) Complexes as Lewis Acids for Catalyzed Cycloaddition, Carbonyl Addition, and Conjugate Addition Reactions

David A. Evans, Tomislav Rovis, Jeffrey S. Johnson

Journal:

Year:

2000

File:

PDF, 26 KB

2000

47

ChemInform Abstract: Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene: A New Enantioselective Carbon—Heteroatom Bond Forming Process.

Mark Lautens, Keith Fagnou, Tomislav Rovis

Journal:

Year:

2000

File:

PDF, 32 KB

2000

48

ChemInform Abstract: Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2-Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate Esters.

David A. Evans, Tomislav Rovis, Marisa C. Kozlowski, C. Wade Downey, Jason S. Tedrow

Journal:

Year:

2001

Language:

english

File:

PDF, 46 KB

english, 2001

49

ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Heteroatom Nucleophiles.

Mark Lautens, Keith Fagnou, Mark Taylor, Tomislav Rovis

Journal:

Year:

2001

File:

PDF, 32 KB

2001

50

ChemInform Abstract: Highly Enantioselective Syntheses of Homopropargylic Alcohols and Dihydrofurans Catalyzed by a Bis(oxazolinyl)pyridine—Scandium Triflate Complex.

David A. Evans, Zachary K. Sweeney, Tomislav Rovis, Jason S. Tedrow

Journal:

Year:

2002

File:

PDF, 33 KB

2002